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1 article(s) from Flood, Amar H.

Creating molecular macrocycles for anion recognition

Amar H. Flood

Beilstein J. Org. Chem. 2016, 12, 611–627, doi:10.3762/bjoc.12.60

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Graphical Abstract

Figure 1: The design and building of a house is just as satisfying as that of a new molecule and often takes ...

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Figure 2: Timeline of anion-binding macrocycles.

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Figure 3: Click chemistry’s copper-catalyzed azide–alkyne cycloaddition (CuAAC) forms 1,2,3-triazoles that st...

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Figure 4: These molecular compounds are the same and not the same.

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Figure 5: (a, b, c) Sequence of chemical sketches leading to triazolophanes. (d) The precursor that led, by C...

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Figure 6: Variation in phenylene substituents weakens chloride affinity from 1 to 4.

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Figure 7: (a) Pyridyl triazolophane and (b) its high-fidelity sandwich around iodide (crystal). Adapted with ...

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Figure 8: Testing the (a) macrocyclic effect, and (b) effect of rigidity against (c) the parent triazolophane....

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Figure 9: (a) Representations of the four equilibria that dominate in dichloromethane for which the (b) propy...

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Figure 10: Representations of (a) aryl–triazole–ether macrocycle 12 and (b) the ion-pair crystal structure of ...

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Figure 11: Chloride is used as a comparator for (a) cyanide and (b) biflouride. (c) Computer-aided receptor de...

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Figure 12: (a) One-pot synthesis of cyanostars. (b) Volcano plot of anion affinities (40:60 methanol/dichlorom...

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Figure 13: (a) Representation and (b) crystal structure of cyanostar-based [3]rotaxane.

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Figure 14: Crystal structures of cyanostar sandwich around (a) perchlorate and (b) diglyme (molecules shown wi...

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Figure 15: (a) Star-extended cyanostar and an (b) STM image cropped from a 2D lamellar lattice. Part (b) adapt...

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Figure 16: (a) Synthesis and one-pot macrocyclization of the tricarb macrocycle. (b) Volcano plot of anion aff...

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Figure 17: (a) Tricarb binds iodide. (b) Tricarb’s single-molecule STM image resembles a donut. (c) Honeycomb ...

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Figure 18: Timeline of crescent-shaped anion receptors.

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Figure 19: Timeline of anion-binding foldamers.

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Figure 20: Family portrait of 3D-printed molecular receptors.

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Review

Published 31 Mar 2016

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